a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)

\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na₂CO₃ hết, CH₃COOH dư

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

                0,15-------->0,3-------------->0,3------->0,15

=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)

b) m_{dd sau pư} = 120 + 53 - 0,15.44 = 166,4 (g)

=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)

nKOH = 0,5.0,3 = 0,15 mol 

CH3COOH + KOH → CH3COOK + H2O

   0,15            0,15         0,15                   mol

a) C_{M CH3COOH} = 0,15/0,2 =0,75M

b) Thể tích của dung dịch thu được sau phản ứng: 500 ml

C_{M CH3COOK} = 0,15/0,5 = 0,3M

c) Phản ứng lên men giấm

C2H5OH + O2 → CH3COOH + H2O

0,15                          0,15

→ mC2H5OH = 0,15.46 = 6,9 gam

\(n_{KOH}=0,5\cdot0,3=0,15mol\)

\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

0,15                     0,15          0,15            0,15

a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)

b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)

Chắc 40g axit axetic là số gam dung dịch nhỉ !

2CH3COOH + CaCO3 => (CH3COO)2Ca + CO2 + H2O

nCO2 = V/22.4 = 0.448/22.4 = 0.02 (mol)

Theo pt ===> nCH3COOH = 0.04 (mol)

mCH3COOH = n.M = 0.04 x 60 = 2.4 (g)

C%ddCH3COOH = 2.4 x 100/40 = 6%

2CH3COOH+Mg->(CH3COO)2Mg+H2

0,02---------------0,01-------0,01----------0,01

n muối=0,01mol

=>CM=\(\dfrac{0,02}{0,04}=0,5M\)

=>VH2=0,01.22,4=0,224l

CH3COOH+NaOH->CH3COONa+H2O

0,02--------------0,02

=>VNaOH=\(\dfrac{0,02}{0,75}=0,03l\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

           0,01<-------0,02<------------0,01------->0,01

=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,04}=0,5M\)

b) V_H2 = 0,01.22,4 = 0,224 (l)

c) 

PTHH: NaOH + CH₃COOH --> CH₃COONa + H₂O

             0,02<------0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,75}=\dfrac{2}{75}\left(l\right)=\dfrac{80}{3}\left(ml\right)\)

\(a.2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\\ n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ n_{CH_3COOH}=2n_{\left(CH_3COO\right)_2Mg}=0,02\left(mol\right)\\ \Rightarrow CM_{CH_3COOH}=\dfrac{0,02}{0,04}=0,5M\\ b.n_{H_2}=n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ \Rightarrow V_{H_2}=0,01.22,4=0,224\left(l\right)\\ c.CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\\ n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\\ \Rightarrow V_{NaOH}=\dfrac{0,02}{0,75}=0,02667\left(l\right)=26,67ml\)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

           0,5        0,25       0,25

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

\(a,m_{ZnCl_2}=0,25.136=34\left(g\right)\)

\(b,m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(m_{ddHCl}=\dfrac{18,25.100}{7,3}=250\left(g\right)\)

\(c,2K+2H_2O\rightarrow2KOH+H_2\uparrow\)

   0,5                                   0,25

\(m_K=39.0,5=19,5\left(g\right)\)

\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ a,n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\Rightarrow n_{CO_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\Rightarrow V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,CH_3COOH+C_2H_5OH⇌\left(H^+,t^o\right)CH_3COOC_2H_5+H_2O\\ n_{CH_3COOH}=\dfrac{50}{200}.0,2=0,05\left(mol\right)\\ n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\ Vì:\dfrac{0,5}{1}>\dfrac{0,05}{1}\Rightarrow Rượu.dư\\ \Rightarrow n_{este\left(LT\right)}=n_{axit}=0,05\left(mol\right)\\ \Rightarrow n_{este\left(TT\right)}=80\%.0,05=0,04\left(mol\right)\\ m_{CH_3COOC_2H_5}=88.0,04=3,52\left(g\right)\)

Rượu etylic \(C_2H_5OH\)

Axit axetic \(CH_3COOH\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)

      0,2                  0,1                 0,2                  0,1         0,1

\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)      

\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)

a)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ --> 2CH₃COONa + CO₂ + H₂O

                 0,2<----------0,1<-------------0,2<-------0,1

=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)

\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)

b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)

\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)

=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)